Complexes of o-phenylenediamine with iron(II) halides have been prepared and characterized by infrared, electronic, and Mössbauer spectroscopy and magnetic susceptibility measurements. Compounds having two, three, four, and six o-phenylenediamine ligands per iron have been isolated. The complexes are all high spin. The infrared data indicate that some of the complexes involve chelated ligands and others unidentate ligands.
G. A. Renovitch and W. A. Baker, J. Chem. Soc. A, 1969, 75 DOI: 10.1039/J19690000075
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