Principles which have been used to explain the ultra-violet spectrum of metal carbonyls M(CO)6 are applied to substituted derivatives of type M(CO)5L, M(CO)4L2. A model is developed which is consistent with the spectra of substituted chromium carbonyls, but not with the photo-electron spectrum of CH3Mn(CO)5.
P. S. Braterman and A. P. Walker, Discuss. Faraday Soc., 1969, 47, 121 DOI: 10.1039/DF9694700121
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