The origin of 1,1- and 1,2-dimethylallyl residues in aryl and heterocyclic compounds is discussed, and the biosynthesis of the 1,2-dimethylallyl derivative, ravenoline, is shown to occur by rearrangement of a 3,3-dimethylallyl ether.
T. R. Chamberlain, J. F. Collins and M. F. Grundon, J. Chem. Soc. D, 1969, 1269b DOI: 10.1039/C2969001269B
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