Some allyl complexes of platinum(II)
Abstract
The compound [Pt2(acac)2(allyl)2] is shown by X-ray diffraction to have the platinum atoms bridged by allyl groups, and n.m.r. shows the complexes [Pt(2-methylallyl)2] and [Pt2Cl2(2-methylallyl)2] to exist as syn- and anti-isomers, with symmetrically bonded π-2-methylallylic groups.