The first metal-pentafluorosulphur(VI) complex, PtCl(SF5)(PPh3)2 has been synthesised, and reactions of pentafluorosulphur chloride and hydrogen fluoride with some complexes of rhodium, iridium, and platinum are described.
R. D. W. Kemmitt, R. D. Peacock and J. Stocks, J. Chem. Soc. D, 1969, 554a DOI: 10.1039/C2969000554A
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