The action of acid on 6-methylthiopurines gave the first imidazole thiol-esters, and 9-methyl-6-methylthio-8-azapurine gave the unusual 1,2,3-triazole thioimidate (III); these have potential value as intermediates.
A. Albert, J. Chem. Soc. D, 1969, 500a DOI: 10.1039/C2969000500A
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