Ultrasonic relaxation has been observed in a number of alkyl-substituted 1,3-dioxans: relaxation of the 2-alkyl derivatives has been attributed to ring inversion, whilst the relaxation found in 2,2,4- and 2,2-substituted derivatives is considered to be the result of the perturbation of a chair–boat equilibrium.
G. Eccleston and E. Wyn-Jones, J. Chem. Soc. D, 1969, 1511 DOI: 10.1039/C29690001511
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