The n.m.r. examination of 3α-methyl-5α-androst-1-ene 3β,19-oxide (2) revealed simultaneous long-range coupling by the two nonequivalent protons of the C-19 methylene group.
A. Guzmán, E. Díaz and P. Crabbé, J. Chem. Soc. D, 1969, 1449 DOI: 10.1039/C29690001449
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