The 1 : 1 adducts of buta-1,3-diene and s- or t-butyl-lithium in hydrocarbon solution have been shown by n.m.r., u.v., and i.r. spectroscopy to be σ-bonded carbon–lithium species of the allyl-lithium type.
W. H. Glaze and P. C. Jones, J. Chem. Soc. D, 1969, 1434 DOI: 10.1039/C29690001434
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