An X-ray crystallographic analysis of tris-(2,2′,6′,2″-terpyridyleuropium(III) perchlorate has confirmed the nona-co-ordination of the metal ion, believed to be the first example of nine-co-ordination involving only nitrogen ligands.
G. H. Frost, F. A. Hart, C. Heath and M. B. Hursthouse, J. Chem. Soc. D, 1969, 1421 DOI: 10.1039/C29690001421
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