In complete contrast to protonation, thermodynamically-controlled alkylation of two simple carbamates with methyl fluorosulphonate occurs on nitrogen: the reasons for this and the results of kinetically-controlled alkylation are discussed.
M. G. Ahmed and R. W. Alder, J. Chem. Soc. D, 1969, 1389 DOI: 10.1039/C29690001389
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