A comparison of two sets of data on the relative rates and isomer ratios of Diels–Alder reactions of 2-substituted butadienes with methyl acrylate and with the methyl acrylate–aluminium chloride complex reveals an excellent Hammett correlation with σ+.
T. Inukai and T. Kojima, J. Chem. Soc. D, 1969, 1334 DOI: 10.1039/C29690001334
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