β-Sultones are formed from the cycloaddition of sulphene with hexahalogenoacetones; however, 1,1,1-trihalogenoacetones do not give the expected adduct but instead yield the novel 1-trihalogenomethylvinyl methanesulphonates.
J. R. Norell, J. Chem. Soc. D, 1969, 1291 DOI: 10.1039/C29690001291
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