In solid-phase peptide synthesis, because of the steric hindrance caused by the polymeric support the choice of activating groups should be directed by experiments carried out on the resin and not by the relative reactivities measured in solution.
M. Bodanszky and R. J. Bath, J. Chem. Soc. D, 1969, 1259 DOI: 10.1039/C29690001259
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