Tetrabenzylzirconium, prepared by reaction of benzylmagnesium chloride with ZrCl4, reacts with HCl gas to give benzylzirconium chlorides; the benzylzirconium compounds show catalytic activity in the polymerization of α-olefins.
U. Zucchini, U. Giannini, E. Albizzati and R. D'Angelo, J. Chem. Soc. D, 1969, 1174 DOI: 10.1039/C29690001174
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