The photolysis of cis- and trans-2,3-dimethylcyclohexanone in methanol–benzene leading via the triplet state to the ester (E) and aldehydes (A) is shown by kinetic analysis probably to proceed through a common discrete biradical (R) which is also responsible for the photoepimerisation: quantitative data bearing on the fate of the biradical are provided.
J. A. Barltrop and J. D. Coyle, J. Chem. Soc. D, 1969, 1081 DOI: 10.1039/C29690001081
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