Incorporation of cyclopropyl and cyclobutyl groups in the 2,3-diazabicyclo[2,2,2]oct-2-ene system has been found to increase the thermoloysis rates by factors of ca. 1017 and 105, respectively.
E. L. Allred and J. C. Hinshaw, J. Chem. Soc. D, 1969, 1021 DOI: 10.1039/C29690001021
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