Dicyanotris-(9-methyl-9-phosphafluorene)nickel(II) and dicyanotris-(9-ethyl-9-phosphafluorene)nickel(II) have tetragonal pyramidal and trigonal bipyramidal configurations, respectively, in the solid state, though in solution they have the same structure.
D. W. Allen, F. G. Mann, I. T. Millar, H. M. Powell and D. Watkin, J. Chem. Soc. D, 1969, 1004 DOI: 10.1039/C29690001004
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