Trans-esterification of chiral secondary carbinols with symmetric nitrite esters occurs readily in polar solvents at 25° without racemization or inversion, and provides a convenient source of chiral nitrite esters for stereochemical studies of optically active alcohols and for photochemical syntheses.
L. D. Hayward and R. N. Totty, J. Chem. Soc. D, 1969, 997 DOI: 10.1039/C29690000997
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