Decaborane, which has not previously been known to act as an oxidizing agent, reacts with Py4FeBr2 in benzene to give a compound which, on treatment with tetrahydrofuran yields the high-spin tetrahedral iron(III) complex py FeBr2B10H13py in high yield.
N. N. Greenwood and H. Schick, J. Chem. Soc. D, 1969, 935 DOI: 10.1039/C29690000935
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