The action of phosgene on sodium t-butyl carbonate gives the crystalline di-t-butyl tricarbonate, m.p. 64–65°, which when subjected to heat breaks down into 3 moles of carbon dioxide, one mole of isobutene and one mole of t-butyl alcohol.
C. S. Dean and D. S. Tarbell, J. Chem. Soc. D, 1969, 728 DOI: 10.1039/C29690000728
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