Stereospecific transmission of electronic effect across the sulphoxide bridge in α-methylbenzyl p-substituted phenyl sulphoxides is attributed to the relative geometry of the proton and the lone pair, in which the difference in the hydridization states is important.
M. Nishio, J. Chem. Soc. D, 1969, 560 DOI: 10.1039/C29690000560
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