Differences in the rate constants for the self-reactions of t-alkylperoxy-radicals are due to differences in the rate constants for irreversible decomposition of the initially formed tetroxides and not to differences in the equilibrium constants for tetroxide formation.
K. Adamic, J. A. Howard and K. U. Ingold, J. Chem. Soc. D, 1969, 505 DOI: 10.1039/C29690000505
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