Cyclopropylamines have been converted into the corresponding N-chloro-amines, which in polar solvents undergo solvolytic cleavage of the N–Cl bond in a heterolytic reaction leading to chloride anion and the nitrogen analogue of the cyclopropylcarbinyl cation.
P. G. Gassman and A. Carrasquillo, J. Chem. Soc. D, 1969, 495 DOI: 10.1039/C29690000495
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