X-Ray crystallographic analysis of ferric tropolone establishes that the iron co-ordination deviates considerably from octahedral, and, in contrast to the cupric tropolone structure, all C–C bonds, apart from the long C(1)–C(2) bond, have lengths near to the aromatic value.
T. A. Hamor and D. J. Watkin, J. Chem. Soc. D, 1969, 440 DOI: 10.1039/C29690000440
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