The ready isomerization of allylically unsaturated di- and poly-sulphides is ascribed to their being in thermal equilibrium with the corresponding isoallylic species having a branched sulphur chain.
D. Barnard, T. H. Houseman, M. Porter and B. K. Tidd, J. Chem. Soc. D, 1969, 371 DOI: 10.1039/C29690000371
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