Equations are derived for the enthalpies of single electrolyte solutions and for the enthalpy and volume changes which occur when pairs of electrolyte solutions are mixed. The results obtained depend upon the basic assumption of Guggenheim regarding the difference in Gibbs function between the electrolyte solution and a standard electrolyte solution. Experimental verification is presented.
T. H. Lilley, Trans. Faraday Soc., 1968, 64, 2947 DOI: 10.1039/TF9686402947
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