The reaction of oxygen atoms generated by mercury-sensitized decomposition of nitrous oxide with the fluoro-olefin yields almost wholly the addition products 2-(trifluoromethyl)-propylene oxide and 2-(trifluoromethyl)-propionaldehyde over the pressure range 10–500mm Hg. The rate constant for the reaction relative to that for butene–1 has been measured as 0.077.
S. J. Moss and K. R. Jennings, Trans. Faraday Soc., 1968, 64, 686 DOI: 10.1039/TF9686400686
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