In mass spectra where the molecular ion abundance is negligible owing to very rapid unimolecular decay of all parent ions, the molecular weight may in principle be determined for a suitable derivative of very low ionization potential.
A. N. H. Yeo and D. H. Williams, J. Chem. Soc. C, 1968, 2666 DOI: 10.1039/J39680002666
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