Grandifolione, isolated from the trunk wood of Khaya grandifoliola, is formulated as (I). It is the first natural representative of a stage regarded as intermediate in the in vivo transformation of apoeuphol (or apotirucallol)(XI) into the typical pentenolide system (XIV) found in limonin.
J. D. Connolly, K. L. Handa, R. McCrindle and K. H. Overton, J. Chem. Soc. C, 1968, 2227 DOI: 10.1039/J39680002227
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