In benzene solution, chloralide has a dipole moment of 1·64 D and a molar Kerr constant of 46 × 10–12. A comparison of these experimental values with those calculated for various possible models suggests that, as a solute, chloralide exists in a conformation in which the CCl3 groups are trans to each other in a non-planar five-membered ring.
L. H. L. Chia and H. H. Huang, J. Chem. Soc. B, 1968, 1369 DOI: 10.1039/J29680001369
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