The band shifts in the i.r. spectra of solid 40–60 %18O enriched sodium deuterioformate show unambiguously that the two C–O force constants are equal and the charge and bond delocalisation in the carboxylate group is complete. This is in contrast to Spinner's conclusion.
H. Junge and H. Musso, J. Chem. Soc. B, 1968, 389 DOI: 10.1039/J29680000389
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