There is a good correlation between the 199Hg-1H coupling constants in RCO2HgMe compounds and the pK values of the acids RCO2H. 199Hg–1H coupling constants in aryl-mercury derivatives parallel quite closely the corresponding 205TI–1H and 1H–1H coupling constants.
D. F. Evans, P. M. Ridout and I. Wharf, J. Chem. Soc. A, 1968, 2127 DOI: 10.1039/J19680002127
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