N-Chloro- or N-bromo-bistrifluoromethylamine undergoes a stepwise substitution reaction with (CF3)3M (M = P, As) to give [(CF3)2N]nP(CF3)3 –n(n= 1, 2, 3) and [(CF3)2N]nAs(CF3)3 –n(n= 1, 2). The corresponding reaction between (CF3)3Sb and (CF3)2NCl gave SbF3, CF3Cl, and CF3N![[double bond, length half m-dash]](https://www.rsc.org/images/entities/char_e006.gif)
CF2. The 19F n.m.r. spectra are recorded.
H. G. Ang and H. J. Emeléus, J. Chem. Soc. A, 1968, 1334 DOI: 10.1039/J19680001334
To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.
If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.
If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.
Read more about how to correctly acknowledge RSC content.
Please wait while we load your content...