Dicarbonylcyclopentadienylrhodium and cyclo-octa-1,5-dienecyclopentadienyliridium form stable 1 : 1 adducts with mercuric chloride and bromide. The adducts are formulated as metal donor–acceptor complexes containing rhodium– or iridium–mercury metal–metal bonds. The infrared spectra of adducts are reported.
J. L. Dawes and R. D. W. Kemmitt, J. Chem. Soc. A, 1968, 1072 DOI: 10.1039/J19680001072
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