Irradiation in the region of the spectra of the M6Cl122+(M = Nb or Ta) cluster claimed to be due to metal–chlorine charge transfer does not increase the rate of chloride release from this cluster. This negative result is significant as it casts doubt on the validity of this assignment of these spectra.
W. van Bronswyk, J. Chem. Soc. A, 1968, 692 DOI: 10.1039/J19680000692
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