Issue 0, 1968
From the journal:

Journal of the Chemical Society A: Inorganic, Physical, Theoretical


Perfluoroalkyl complexes of palladium and platinum

D. T. Rosevear  and  F. G. A. Stone  

Abstract

Treatment of the zero-valent platinum or palladium complexes (Ph3P)4M or (Ph2PCH2CH2PPh2)2M with perfluoroalkyl iodides represents a convenient synthesis of the perfluoroalkyl(iodo)-compounds (Ph3P)2M(RF)I or diphosM(RF)I (RF= CF3, C2F5, or C3F7). The new compounds are somewhat insoluble in organic solvents, but are stable in air. An oxidative-addition reaction also occurs between pentafluorobenzoyl chloride and tetrakis(triphenylphosphine)platinum.

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Article information

DOI
https://doi.org/10.1039/J19680000164
Article type
Paper

J. Chem. Soc. A, 1968, 164-167

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Perfluoroalkyl complexes of palladium and platinum

D. T. Rosevear and F. G. A. Stone, J. Chem. Soc. A, 1968, 164 DOI: 10.1039/J19680000164

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