The current-time relationship is derived for the following reaction scheme for electrocrystallization: A discussion of the limiting cases for potentiostatic experiments is presented. The corresponding results for the relaxation techniques (particularly the faradaic impedance) are also obtained.
M. Fleischmann, S. K. Rangarajan and H. R. Thirsk, Trans. Faraday Soc., 1967, 63, 1256 DOI: 10.1039/TF9676301256
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