High-temperature catalytic reductive amination of 2-hydroxy-1,6-hexanedial in ethanol gives low yields of mixtures of heterocyclic bases including 2-aminomethylpiperidine, 2-ethylaminomethylpiperidine, and related compounds. In aqueous medium 2-aminomethylpiperidine and probably 2-hydroxymethylpiperidine are produced.
D. H. Johnson, J. Chem. Soc. C, 1967, 1284 DOI: 10.1039/J39670001284
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