The acetolysis of benzyl ethers of myoinositol is selective and its rate varies with the nature and configuration of the neighbouring groups. The penta-acetate of 1-O-benzylmyoinositol is readily obtained from 1,4,5,6-tetra-O-benzylmyoinositol; hydrogenolysis gives 1,2,4,5,6-penta-O-acetylmyoinositol.
S. J. Angyal, M. H. Randall and M. E. Tate, J. Chem. Soc. C, 1967, 919 DOI: 10.1039/J39670000919
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