The kinetics for the hydrolysis of trinitrodiethylenetriaminecobalt(III) and the tetranitroethylenediaminecobalt(III) anion have been studied at 0° in aqueous solutions containing varying amounts of alkali; the hydrolyses are of the second- and first-order, respectively. Arguments are presented against the conjugate-base mechanism of base hydrolysis of cobaltammine complexes in aqueous solutions.
S. C. Chan and P. Y. Leung, J. Chem. Soc. A, 1967, 2089 DOI: 10.1039/J19670002089
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