The addition of fluorine to phosphorus trichloride leads to the formation of trichlorodifluorophosphorane along with solid ionic chlorofluorides of phosphorus(V), largely [PCl4]+Fâ and [PCl4]+[PF6]â. The reactions of trichlorodifluorophosphorane with triethylamine and triethylphosphine yield a complex mixture of products.
T. Kesavadas and D. S. Payne, J. Chem. Soc. A, 1967, 1001 DOI: 10.1039/J19670001001
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