The formal oxidation–reduction potential of the couple Co(C2O4)33–+ e–= Co(C2O4)34– is 0·57 V at ionic strength 1·0M with potassium chloride as the main supporting electrolyte. The titration of trioxalatocobaltate(III) with dilute hydrochloric acid shows that this complex is dominantly in the trisbidentate form in aqueous solution.
L. Hin-Fat and W. C. E. Higginson, J. Chem. Soc. A, 1967, 298 DOI: 10.1039/J19670000298
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