The observed shifts in the C—D stretching frequency in mixtures of base and deuterochloroform have been used to compare the donor properties of a variety of organometallic bases. These include ethers, sulphides and amines in which one or more (CH3)3 M-groups (M = Si, Ge, Sn or Pb), are attached to the donating atom.
E. W. Abel, D. A. Armitage and D. B. Brady, Trans. Faraday Soc., 1966, 62, 3459 DOI: 10.1039/TF9666203459
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