Volume 62, 1966

Thermochemistry of reductions caused by lithium aluminium hydride. Part 4.—Heat of formation of methyl bromide

Abstract

The heat of reduction of methyl bromide by an ethereal solution of lithium aluminium hydride has been studied in an adiabatic calorimeter. From the reaction heat we obtain ΔH°(CH3Br, g)=–9.0±0.3 kcal/mole, and D(CH3—Br)= 66.7±2 kcal/mole, relative to the C—H dissociation energy, D(CH3—H)= 102±2 kcal/mole.

Article information

Article type
Paper

Trans. Faraday Soc., 1966,62, 1447-1449

Thermochemistry of reductions caused by lithium aluminium hydride. Part 4.—Heat of formation of methyl bromide

G. P. Adams, A. S. Carson and P. G. Laye, Trans. Faraday Soc., 1966, 62, 1447 DOI: 10.1039/TF9666201447

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