The heat of reduction of methyl bromide by an ethereal solution of lithium aluminium hydride has been studied in an adiabatic calorimeter. From the reaction heat we obtain ΔH°(CH3Br, g)=–9.0±0.3 kcal/mole, and D(CH3—Br)= 66.7±2 kcal/mole, relative to the C—H dissociation energy, D(CH3—H)= 102±2 kcal/mole.
G. P. Adams, A. S. Carson and P. G. Laye, Trans. Faraday Soc., 1966, 62, 1447 DOI: 10.1039/TF9666201447
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