E.p.r. evidence is obtained for reduced silver ions, Ag° and Ag+2, and oxidized silver ions, Ag2+, in γ-irradiated frozen solution. The reducing species is attributed to mobile electrons which are chemically trapped by the solute, and the oxidizing species to the hydroxyl radical and the SO–4 radical.
L. Shields, Trans. Faraday Soc., 1966, 62, 1042 DOI: 10.1039/TF9666201042
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