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Volume 62, 1966
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Ring inversion of some 1,3-dioxanes


Thermodynamic parameters have been determined for the chair-to-boat isomerization of 1,3-dioxane, its 2,2- and 5,5-dimethyl, and 2,2,5,5-tetramethyl-derivatives, in acetone or dichlorodi-fluoromethane solution in the temperature range 120–235°K. The significance of the results is discussed.

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Article information

Trans. Faraday Soc., 1966,62, 39-45
Article type

Ring inversion of some 1,3-dioxanes

J. E. Anderson and J. C. D. Brand, Trans. Faraday Soc., 1966, 62, 39
DOI: 10.1039/TF9666200039

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