(–)-3α-Tigloyloxy-6β-acetoxytropane has been identified as a component of the alkaloidal mixture of Datura sanguinea leaves and young stems. Its structure was indicated by spectroscopy and by hydrolysis and confirmed by partial synthesis. 3α-Acetoxytropane, not previously recorded as a natural product, has also been isolated from the same plant material.
W. C. Evans and V. A. Major, J. Chem. Soc. C, 1966, 1621 DOI: 10.1039/J39660001621
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