Issue 0, 1966

Some reactions of dialkylamino radicals

Abstract

The photolyses of tetramethyltetrazen and 1,1′-azopiperidine have been effected in some hydrocarbon solvents and the extent of the general reaction R2N·+ H–X R2NH +·X has been examined by product study: radicals R2N· prove to be but feeble dehydrogenating agents. Dimethylamino radicals do not dehydrogenate either 2,6-dimethoxy- or 2,6-dimethyl-phenol. Slight evidence of addition to anthracene was obtained. Attempts to prepare a radical R2N· from 2,2,6,6-tetramethylpiperidine have been unsuccessful.

Article information

Article type
Paper

J. Chem. Soc. C, 1966, 813-816

Some reactions of dialkylamino radicals

D. Mackay and W. A. Waters, J. Chem. Soc. C, 1966, 813 DOI: 10.1039/J39660000813

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