A three-dimensional crystal structure analysis of the title compound (Me3CNBNCS)4 shows that the molecule contains an eight-membered ring of alternate boron and nitrogen atoms. The ring is in the tub conformation and there are localised π-bonds between alternate pairs of atoms.
P. T. Clarke and H. M. Powell, J. Chem. Soc. B, 1966, 1172 DOI: 10.1039/J29660001172
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